Ammonia decomposition catalysis using non-stoichiometric lithium imide† †Electronic supplementary information (ESI) available: Data analysis procedures, data fitting procedures, X-ray diffraction pattern of Li2ND, details of reduction of LiND2 unit cell, POLARIS blank cell results, NPD patterns, exponential fits to QGA data and long-duration reaction data. See DOI: 10.1039/c5sc00205b

Mixed-valent, heteroleptic homometallic diketonates as templates for the design of volatile heterometallic precursors† †Electronic supplementary information (ESI) available: Experimental procedures, synthetic details, IR spectra, X-ray powder diffraction patterns, computational details, TEM images and phase analysis of thermal decomposition products. CCDC 1040548–1040553. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc04002c

Ammonia decomposition catalysis using non-stoichiometric lithium imide.

We demonstrate that non-stoichiometric lithium imide is a highly active catalyst for the production of high-purity hydrogen from ammonia, with superior ammonia decomposition activity to a number of other catalyst materials. Neutron powder diffraction measurements reveal that the catalyst deviates from pure imide stoichiometry under ammonia flow, with active catalytic behaviour observed across a...

Hydrogen bonding vs. halogen bonding: the solvent decides† †Electronic supplementary information (ESI) available: Full details of all experimental procedures and analysis of NMR spectroscopic data, powder X-ray data and single-crystal X-ray diffraction data. CCDC 1478819 and 1478820, for compounds 2b·3 and 2c·3 contain the supplementary crystallographic data for this paper. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01801k Click here for additional data file. Click here for additional data file.

Department of Chemistry, University of She E-mail: [email protected] Department of Chemistry, University of Y E-mail: [email protected] Department of Chemistry, University of Ca 1EW, UK. E-mail: [email protected] † Electronic supplementary information experimental procedures and analysis of data and single-crystal X-ray diffraction compounds 2b$3 and 2c$3 contain the s this paper....

Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate, B-(cyclotriborazanyl)amine-borane† †Electronic supplementary information (ESI) available: Experimental procedures, X-ray and NMR data. CCDC 1022830 and 1022831. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02710h Click here for additional data file. Click here for additional data file.

Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin† †Electronic supplementary information (ESI) available: General procedures, synthetic details, NMR spectra, EPR spectra, IR spectra, electronic absorption and emission spectra, voltammetric data, X-ray crystallographic data, computational details and optimised geometries. CCDC 1446511, 1446512 and 1507634. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc02912d Click here for additional data file. Click here for additional data file.

EaStCHEM School of Chemistry, The Unive David Brewster Road, Edinburgh, EH9 3FJ, [email protected] LPCNO, INSA, Université de Toulouse, 13 cedex 4, France Centre for Radiochemisty Research, Sch Manchester, Oxford Road, Manchester, M13 WestCHEM School of Chemistry, University † Electronic supplementary information synthetic details, NMR spectra, EPR spe and emission spectra, voltammetric computati...